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Ono, Masao; Huang, X. S.*; Shibata, Yasuhiro*; Iguchi, Yusuke*; Sakai, Seiji; Maekawa, Masaki; Chen, Z. Q.*; Osakabe, Toyotaka; Kawasuso, Atsuo; Naramoto, Hiroshi*; et al.
Proceedings of 1st International Conference on Diffusion in Solids and Liquids (DSL 2005), p.531 - 533, 2005/07
Recently, we formed atomic-scale graded structures in some miscible alloys and observed the decomposition in BiPb intermetallic compound by sedimentation of atoms under strong gravitational field. In this study, we measured positron lifetime of centrifuged BiPb, to which the composition change was very small as it was treated at low temperature. It was found that the positron lifetime became longer than that of starting state. This indicated that the point defects (vacancy or divacancy) increased in the sample by centrifugal treatment. We are now investigating the relationship between increase in point defects and sedimentation of atoms.
Ono, Masao; Kinoshita, Takahiro*; Ueno, Hideto*; Huang, X.*; Osakabe, Toyotaka; Mashimo, Tsutomu
Materials Transactions, 46(2), p.219 - 224, 2005/02
Times Cited Count:8 Percentile:54.95(Materials Science, Multidisciplinary)Ultracentrifuge experiments were performed on the In-Pb system to study the sedimentation of atoms and phase equilibrium. After the experiments, the graded structures were obtained. Pb-rich phase (f.c.c) and In-rich phase (tetragonal) appeared at the strong- and weak-gravitational field sides of the sample, respectively, from starting state of -phase. And, the continuous changes in lattice parameters were observed in each phase. These observation results showed that the graded structure was continuous in atomic scale, and was formed by the sedimentation of atoms. Composition profiles of the centrifuged samples for 31.3 h, 60 h and 150 h showed that the composition change reached the steady state within 60 hours. The diffusion coefficient for sedimentation was estimated to be about 8 times larger than that for usual diffusion by the simulation. The result indicated that the diffusion mechanism of the sedimentation was different from the conventional ones.
Ono, Masao; Huang, X.*; Kinoshita, Takahiro*; Ueno, Hideto*; Osakabe, Toyotaka; Mashimo, Tsutomu
Defect and Diffusion Forum, 237-240(2), p.1101 - 1104, 2005/00
Ultra-strong gravitational field can induce sedimentation of even atoms in condensed matter. We had realized sedimentation of substitutional solute atoms in some miscible alloys. How about in the other alloys? So, In this study, the ultra-centrifuge experiments were performed on an intermetallic compound of Bi-Pb system (BiPb) by changing time duration of experiment time (experimental conditions; maximum centrifugal force: 1.010g level, temperature: 130-150 C, duration: 30-150h, state: solid). Composition changes were observed in the centrifuged samples. And, it was found that the Bi phase appeared from starting state of BiPb around the weak gravitational field region of the sample. These results showed that sedimentation of substitutional solute atoms occurred, and induced the structure change in intermetallic compounds.
Oda, Tetsuzo
JAERI-M 93-052, 49 Pages, 1993/03
no abstracts in English
Nishimura, Hideo
JAERI-M 91-219, 98 Pages, 1992/01
no abstracts in English
Okamoto, Tsuyoshi*; Nishimura, Hideo
JAERI-M 90-031, 89 Pages, 1990/02
no abstracts in English
Nishimura, Hideo; Okamoto, Tsuyoshi*
31st Annual Meeting Proc. of Nuclear Materials Management,Vol. 19, p.518 - 523, 1990/00
no abstracts in English
Okamoto, Tsuyoshi*; *; Nishimura, Hideo
JAERI-M 89-059, 18 Pages, 1989/05
no abstracts in English
Fujine, Sachio; M.Kluth*; J.Lamla*; H.Goldacker*
Proc. of the Symp. on Solvent Extraction 1989, p.141 - 146, 1989/00
no abstracts in English
;
Journal of Radioanalytical and Nuclear Chemistry, 84(2), p.269 - 275, 1984/00
Times Cited Count:6 Percentile:57.41(Chemistry, Analytical)no abstracts in English
JAERI-M 9173, 42 Pages, 1980/11
no abstracts in English